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Atomic Radius in the Periodic Table Explained

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How Does Atomic Radius Change Across Periods and Groups?

The concept of Atomic Radius in Periodic Table in Basic Chemistry is essential in chemistry and helps explain reactions, equations, and real-world chemical processes effectively.


Understanding Atomic Radius in Periodic Table in Basic Chemistry

Atomic Radius in Periodic Table in Basic Chemistry refers to the size of an atom, typically measured from the center of the nucleus to the outermost electron shell. This concept is important in areas like periodic table trends, chemical bonding, and electronic configuration. Understanding atomic radius helps students predict element behavior, bond strength, and reactivity.


Types of Atomic Radius

Atomic radius can be measured in different ways, each relevant for specific scenarios:

  • Covalent Radius: Distance between nuclei of two bonded atoms in a molecule.
  • Metallic Radius: Half the distance between nuclei of adjacent atoms in a metallic lattice.
  • Van der Waals Radius: Half the distance between nuclei of two non-bonded atoms in a solid.
  • Ionic Radius: Effective distance from nucleus to outermost shell in an ion.

Atomic Radius Trends in Periodic Table

Atomic radius in the periodic table shows clear patterns:

  • Across a Period (Left to Right): Atomic radius decreases due to increasing nuclear charge, pulling electrons closer.
  • Down a Group (Top to Bottom): Atomic radius increases as additional electron shells are added.

These patterns help students compare atomic size and predict chemical properties more easily during exams.


Sample Diagram: Atomic Radius Trend

  • → Across Period: Decreases (e.g., Na > Mg > Al > Si > P > S > Cl > Ar)
  • ↓ Down Group: Increases (e.g., Li < Na < K < Rb < Cs)

Here’s a helpful table to understand atomic radius values for some elements:


Atomic Radius in Periodic Table in Basic Chemistry Table

Element Atomic Radius (pm) Trend in Table
Hydrogen (H) 53 Smallest in Group 1
Lithium (Li) 167 First in 2nd period, large in period
Sodium (Na) 190 Increases down group
Chlorine (Cl) 79 Decreases across period
Cesium (Cs) 260 Largest stable element

Atomic Radius Formula / Calculation

There is no single fixed formula for atomic radius, but it is often calculated using:

  • Covalent Radius = (Distance Between Nuclei of Two Same Atoms) / 2

Units are usually picometers (pm) or angstroms (Å).


Worked Example – Chemical Calculation

Let’s understand the process step by step:


1. Suppose two chlorine atoms in a Cl2 molecule are 198 pm apart.

2. Covalent radius of chlorine = 198 pm / 2 = 99 pm.

Final Understanding: The atomic radius can be calculated when the interatomic distance is known from experimental data.


Applications and Exceptions

  • Trends in atomic radius help explain ionization energy and electronegativity trends.
  • Exception: Transition metals and noble gases may deviate slightly from general trends due to electron configuration.
  • Atomic radius affects bond length, molecule size, and chemical reactivity.
  • In chemical bonding, atomic size determines bond type and length.

Practice Questions

  • Define Atomic Radius in Periodic Table in Basic Chemistry and give an example.
  • What is the chemical significance of atomic radius trends?
  • How is atomic radius applied in real-world chemistry?
  • Write the formula for covalent radius calculation.

Common Mistakes to Avoid

  • Confusing atomic radius with atomic mass or atomic number.
  • Using incorrect formulas for different types of radii (ionic, covalent, etc.).
  • Incorrectly applying the trends for periods or groups, especially with exceptions.

Real-World Applications

The concept of Atomic Radius in Periodic Table in Basic Chemistry is widely used in pharmaceuticals, materials science, environmental studies, and industrial chemistry. Vedantu connects such topics to real-life chemical understanding. It also helps students excel in exams such as NEET and JEE by mastering periodic trends and conceptual clarity.


In this article, we explored Atomic Radius in Periodic Table in Basic Chemistry, its definition, real-life relevance, and how to solve related problems. Continue learning with Vedantu to master such chemistry topics.


For further reading, check out these topics:


FAQs on Atomic Radius in the Periodic Table Explained

1. What is atomic radius in the chemistry periodic table?

Atomic radius refers to the size of an atom, specifically the distance from the nucleus to the outermost electron shell. Understanding atomic radius is crucial for predicting chemical properties and trends in the periodic table. It helps explain reactivity, bonding, and other characteristics of elements.

2. What is atomic radius in Class 12th chemistry?

In Class 12 chemistry, atomic radius is a fundamental concept used to understand periodic trends and predict the properties of elements. It's essential for solving problems related to chemical bonding, reactivity, and the periodic table. You'll need to know how atomic radius varies across periods and groups.

3. What is the order of atomic size in the periodic table?

Atomic radius generally decreases across a period (from left to right) due to increasing nuclear charge and a relatively constant shielding effect. It generally increases down a group (from top to bottom) because of the addition of electron shells. However, there are exceptions, particularly in transition metals.

4. What are the four types of atomic radius?

The four main types are: covalent radius (half the distance between two covalently bonded atoms), metallic radius (half the distance between two adjacent metal atoms), van der Waals radius (half the distance between two non-bonded atoms), and ionic radius (the radius of an ion).

5. How to determine atomic size on the periodic table?

You determine atomic size by considering its position within the periodic table. Atomic size generally increases down a group and decreases across a period. However, remember there are exceptions to this trend. Understanding electron shielding and effective nuclear charge helps explain these variations.

6. What is the atomic radius trend in the periodic table?

The atomic radius trend shows a general decrease across a period (left to right) and an increase down a group (top to bottom). This is primarily due to the balance between increasing nuclear charge and electron shielding. However, the transition metals show irregularities in this trend.

7. How does atomic size change across periods and groups?

Across a period, atomic size decreases due to increased effective nuclear charge pulling electrons closer to the nucleus. Down a group, atomic size increases because new electron shells are added, increasing the distance of outermost electrons from the nucleus.

8. What are some exceptions to the atomic radius trend?

Exceptions to the general trend often occur with transition metals. The incompletely filled d-orbitals result in variations in effective nuclear charge, leading to less predictable changes in atomic size. Noble gases also show slight deviations.

9. How does atomic radius affect chemical bonding?

Atomic radius significantly impacts chemical bonding. Smaller atoms tend to form stronger bonds because the electrons are closer to the nucleus, leading to stronger electrostatic attraction. The size also influences bond length and the geometry of molecules.

10. What is the atomic radius of hydrogen?

The atomic radius of hydrogen is relatively small compared to other elements due to its single proton and electron. Its unique position in the periodic table makes its atomic radius exceptional and requires separate consideration from other elements. It’s important to remember that its radius will depend on whether covalent or van der Waals radius is being considered.

11. What is the difference between atomic radius and atomic size?

While often used interchangeably, atomic radius is a more precise term, referring to the distance from the nucleus to the outermost electron shell. Atomic size is a broader concept encompassing the overall dimensions of an atom. The difference can be subtle, but the term radius usually implies a specific measurement.

12. How does knowing atomic size help solve periodic table problems?

Understanding atomic size trends helps in predicting properties like reactivity, ionization energy, and electronegativity. It is also crucial for predicting the nature of chemical bonds formed by different elements and the overall properties of molecules and compounds. Knowledge of atomic size is vital for solving many periodic table problems in competitive exams such as JEE and NEET.